Perfect thoracic extension on the DL is not always 100% critical for a good pull or even for safety. It should be held RIGID, but a little bit of rounding is acceptable at max effort. If its egregious or if it is actively moving into greater and greater flexion during the pull then you may be at more risk. Some good lifters pull with a lot of rounding in the thoracic just fine.
Don't do Rack Pulls or haltings on Monday if you are gonna DL heavy on Friday. RDLs are fine. BB Rows may help some, but probably more of a technique/coaching/cue issue than something correctable with another exercise.