I think Rip has answered this question before but can't find details. Generally I believe as an a approximate guide 5x5 + 10% = 1x5 + 10% = 1RM. So 3x5 might be a 6-7% increase to 1x5. Obviously take into account if belted on all reps and your trainees experience in attempting a 1RM which is a skill in itself.