Your right shoulder is flexed more than your left, at least that's how it appears in the pictures you have provided.
Possible causes? Many, but the first one to rule out is whether it's an instinctive bad-habit. See if you can correct it next time you are near a bench by trying to extend both shoulders equally (use the camera, see if there's an improvement when you go in conscious of what I've highlighted). In the frontal photo you posted, there's some lateral displacement going on, possibly scoliosis, but could be something else, have you ever suffered any injuries on the right side of your body? Ever had a job that's required carrying physical loads with your left side?